The elusive three-coordinate dicationic hydrido boron complex.
نویسندگان
چکیده
The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 136 3 شماره
صفحات -
تاریخ انتشار 2014